Personally, I don't even think Chun Li's worth bothering with in this game, as she's at her worst in it, but I'll tell you one super; for the big chi blast when you're player 1, press s, d, then all 3 punch button. When you're player 2, press s, a and all 3 punch buttons. I believe that's the motion, but I've only used her in practice, so if anyone wants to help this person out with more advice than my paltry offering, go ahead.
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